I've been very happy with the quality of the paint on my 545i--both appearance (not too much orange peel) and durability. In fact, compared to Porsches and Mercedes I've owned, I find it to be more durable.
Car manufacturers for many years have been using water based paints (due to environmental issues) which are not as durable as the solvent based paints formerly used. The BMW paint process includes drying/curing at high temps, and the clear coat is a powder based paint, which is melted in an oven to achieve the smooth, clear finish. Here's the Dingolfing plant website--click on production, paintshop for info:
http://www.bmw-plant-dingolfing.com/dingolfing/htdocs/lowband/com/en/index.html
Car manufacturers for many years have been using water based paints (due to environmental issues) which are not as durable as the solvent based paints formerly used. The BMW paint process includes drying/curing at high temps, and the clear coat is a powder based paint, which is melted in an oven to achieve the smooth, clear finish. Here's the Dingolfing plant website--click on production, paintshop for info:
http://www.bmw-plant-dingolfing.com/dingolfing/htdocs/lowband/com/en/index.html