I know this was covered recently, and I stated that for me "petrol is petrol" and the cheaper the better with the miles I drive.
BUT the petrol seemed to have droped about 3p a litre around here - so standard unleaded around 90.9-91.9. Well I had a Tesco 5p off a litre token, and they had 99RON at 95.9, which seemed pretty reasonable (90.9 with my token) so I thought I might give the 99RON a go, and was well sceptical - convinced I would feel no difference.
But as soon as I started it I noticed quite a big difference - it started easier and smoother, and lower rpm is soo much smoother now. Also feels smoother from a cold start today as well. Can't notice any performance difference at all. Also I notice no difference over 4000rpm.
The big difference may be as I have a non-OEM chip in now that may perhaps be expecting higher RON, but I was very, very surprised!